Enantioselective synthesis of alcohols and aminoalcohols via rhodium- and ruthenium-mediated asymmetric transfer hydrogenation
Synthese enantioselective d'alcools et d'aminoalcools par transfert d'hydrogene asymetrique catalyse par le rhodium et le ruthenium
Abstract
1. Synthesis of a new family of Rhodium-tethered Catalysts and their application in asymmetric transfer hydrogenation of ketones 2. Enantio- and diastereoselective synthesis of 2-(1,2,3,4-tetrahydro-1-iso-quinolyl)ethanol derivatives via asymmetric transfer hydrogenation through dynamic kinetic resolution 3. Asymmetric transfer hydrogenation/dynamic kinetic resolution: application to the synthesis of enantioenriched 1,2-diols and 1,2-amino alcohols.
1.Synthese d'une nouvelle famille de catalyseurs a base de rhodium et leurs applications en transfert d'hydrogene asymetrique. 2. Syntheses enantio- et diastereo-selectives de derives 2-(1,2,3,4-tetrahydro-1-iso-quinolyl) ethanol par transfert d'hydrogene asymetrique et dedoublement cinetique dynamique. 3. Transfert d'hydrogene asymetrique associe au dedoublement cinetique dynamique : application a la synthese de diols 1,2 et d'amino-alcools 1,2 enantioenrichis.
Origin : Version validated by the jury (STAR)